119987-30-3

Upstream product

• 117155-21-2 (3Z,7E)-4-Dimethoxymethyl-8-methyl-10-(2,6,6-trimethyl-cyclohex-1-enyl)-1-(5-trimethylsilanyl-furan-3-yl)-deca-3,7-dien-1-one 

Downstream Products

• 105426-92-4 4-[(3Z,7E)-4-Dimethoxymethyl-1-(1-ethoxy-ethoxy)-8-methyl-10-(2,6,6-trimethyl-cyclohex-1-enyl)-deca-3,7-dienyl]-5-hydroxy-5H-furan-2-one 
• 75088-80-1 manoalide 
• 105498-76-8 seco-manoalide 
• 105426-91-3 {4-[(3Z,7E)-4-Dimethoxymethyl-1-(1-ethoxy-ethoxy)-8-methyl-10-(2,6,6-trimethyl-cyclohex-1-enyl)-deca-3,7-dienyl]-furan-2-yl}-trimethyl-silane 

Relevant academic research and scientific papers

HIGHLY EFFICIENT TOTAL SYNTHESIS OF MANOALIDE AND SECO-MANOALIDE VIA Pd(0) CATALYZED COUPLING OF ALLYLHALIDE WITH CO AND 2-SILYL-4-STANNYLFURAN

Total synthesis of manoalide and seco-manoalide from an allylchloride derivative was achieved by 6 steps in 56.4percent overall yield by Pd(0) catalyzed coupling with CO and 2-trimethylsilyl-4-tributylstannylfuran followed by chemoselective oxidation of 2-trimethylsilylfuran with 1O2.