1200-71-1Relevant articles and documents
The Hydrolysis of the Anhydride of 2-Cyano-2-phenylpropanoic Acid Triggers the Repeated Back and Forth Motions of an Acid–Base Operated Molecular Switch
Biagini, Chiara,Capocasa, Giorgio,Cataldi, Valerio,Del Giudice, Daniele,Mandolini, Luigi,Di Stefano, Stefano
supporting information, p. 15205 - 15211 (2019/11/14)
This work aimed to render phenomenologically autonomous the otherwise stepwise operation of a catenane-based molecular switch, which is chemically triggered by the decarboxylation of 2-cyano-2-phenylpropanoic acid (2). Given that any amount of 2 in stoich
Photoinduced Release of a Chemical Fuel for Acid–Base-Operated Molecular Machines
Biagini, Chiara,Di Pietri, Flaminia,Mandolini, Luigi,Lanzalunga, Osvaldo,Di Stefano, Stefano
, p. 10122 - 10127 (2018/07/29)
Back and forth motions of the acid–base-operated molecular switch 1 are photo-controlled by irradiation of a solution, which also contains the photolabile pre-fuel 4. The photo-stimulated deprotection of the pre-fuel produces controlled amounts of acid 2,