120093-92-7

Upstream product

• 5100-98-1 1-chloro-2-iodo-3-methylbenzene 
• 49750-22-3 1-(trimethylsilyl)vinylmagnesium bromide 
• 615-65-6 2-chloro-4-methyl-benzenamine 
• 87-63-8 2-chloro-6-methylaniline 
• 585-74-0 3-Methylacetophenone 
• 116632-42-9 2-chloro-1-iodo-4-methylbenzene 

Downstream Products

• 123-54-6 acetylacetone 
• 100-70-9 2-Cyanopyridine 
• 108-20-3 di-isopropyl ether 

Relevant academic research and scientific papers

Preparation of Optically Active cis-Cyclopropane Carboxylates: Cyclopropanation of α-Silyl Stryenes with Aryldiazoacetates and Desilylation of the Resulting Silyl Cyclopropanes

Optically active cis-cyclopropane carboxylates are prepared via the Rh2(S-PTAD)4-catalyzed cyclopropanation of α-silyl styrenes with aryl diazoacetates followed by desilylation of the resulting silyl cyclopropane carboxylates. The co

VINYLSILYL GRIGNARD REAGENTS AS ARYNE TRAPS. A NEW ROUTE TO (ARYLALKENYL)SILANES.

A general method for preparing (arylalkenyl)silanes via nucleophilic capture of arynes with vinyltrimethylsilyl Grignard reagents is decribed.