120104-57-6

Basic information

• Product Name: 3'-bis(1,1,1,3,3,3-hexafluoro-2-propyl)phosphite
• Synonyms: 3'-bis(1,1,1,3,3,3-hexafluoro-2-propyl)phosphite
• CAS NO: 120104-57-6
• Molecular Formula: C₆H₃F₁₂O₃P
• Molecular Weight: 381.0328794
• Mol File: 120104-57-6.mol
• Article Data: 3

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: 3'-bis(1,1,1,3,3,3-hexafluoro-2-propyl)phosphite(CAS DataBase Reference)
• NIST Chemistry Reference: 3'-bis(1,1,1,3,3,3-hexafluoro-2-propyl)phosphite(120104-57-6)
• EPA Substance Registry System: 3'-bis(1,1,1,3,3,3-hexafluoro-2-propyl)phosphite(120104-57-6)

Safety Data

• Hazardous Substances Data: 120104-57-6(Hazardous Substances Data)

Upstream product

• 920-66-1 1,1,1,3',3',3'-hexafluoro-propanol 

Downstream Products

• 66470-81-3 tris(1,1,1,3,3,3-hexafluoroisopropyl)phosphite 
• 130288-81-2 5'-O-dimethoxytrityl-2'-deoxythymidine-3'-H-phosphonate 

Relevant articles and documents

The first isolable dialkyl iodophosphates

The synthesis and characterization of the first dialkyl iodophosphates to be isolated in a pure state is described; (CF3CH2O)2P(O)I and [(CF3)2CHO]2P(O)I have electronegative fluoro-ester groups and can be distilled under vacuum.

DISPROPORTIONATION OF BIS(FLUOROALKYL) HYDROGEN PHOSPHITES TO TRIS(FLUOROALKYL) PHOSPHITES UNDER THE ACTION OF BASES

Bis(fluoroalkyl) hydrogen phosphites formed by the reaction of PCl3 with fluorinated alcohols in the presence of water undergo disproportionation under the action of triethylamine to form tris(fluoroalkyl) phosphites and triethylammonium fluoroalkyl hydrogen phosphites.The reaction mechanism is discussed.