1201411-19-9Relevant academic research and scientific papers
Electrocatalytic fluoroalkylation of olefins
Mikhaylov,Budnikova,Gryaznova,Krivolapov,Litvinov,Vicic,Sinyashin
, p. 3840 - 3843 (2009)
An efficient nickel-catalyzed method devoted to the direct addition of perfluoroalkyl halides (I, Br) to α-methylstyrene is described. This procedure allows for synthesis of compounds resulting from addition-dimerization in good yields.
Electrochemical nickel-induced fluoroalkylation: Synthetic, structural and mechanistic study
Mikhaylov, Dmitry,Gryaznova, Tatyana,Dudkina, Yulia,Khrizanphorov, Mikhail,Latypov, Shamil,Kataeva, Olga,Vicic, David A.,Sinyashin, Oleg G.,Budnikova, Yulia
scheme or table, p. 165 - 172 (2012/01/31)
Electrocatalytic generation of nickel catalysts in low oxidation states by reduction of nickel complexes with various ligands (2,2′-bipyridine, 2,2′:6′,2′′-terpyridine, (S,S)-2,6-bis(4-phenyl-2- oxazolin-2-yl)-pyridine) in the presence of olefinic substra
Electrocatalytic fluoroalkylation of olefins
Mikhaylov,Gryaznova,Budnikova,Sinyashin
experimental part, p. 1918 - 1920 (2011/07/08)
Under electrocatalysis conditions, the perfluoroalkylation of α-methylstyrene by the nickel complex NiBr2bipy proceeds with the formation of dimeric products of addition of perfluoroalkyl radicals to the double bond.
