120157-60-0

Basic information

• Product Name: 2,3-O-(3-PENTYLIDENE)-D-GLYCERALDEHYDE
• Synonyms: 2,3-O-(3-PENTYLIDENE)-D-GLYCERALDEHYDE;1,3-Dioxolane-4-carboxaldehyde, 2,2-diethyl-, (4R)- (9CI);(R)-2,2-diethyl-1,3-dioxolane-4-carbaldehyde
• CAS NO: 120157-60-0
• Molecular Formula: C₈H₁₄O₃
• Molecular Weight: 158.19
• Product Categories: ALDEHYDE
• Mol File: 120157-60-0.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 209.4°Cat760mmHg
• Flash Point: 70.6°C
• Appearance: /
• Density: 1.047g/cm³
• Vapor Pressure: 0.204mmHg at 25°C
• Refractive Index: 1.471
• CAS DataBase Reference: 2,3-O-(3-PENTYLIDENE)-D-GLYCERALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-O-(3-PENTYLIDENE)-D-GLYCERALDEHYDE(120157-60-0)
• EPA Substance Registry System: 2,3-O-(3-PENTYLIDENE)-D-GLYCERALDEHYDE(120157-60-0)

Safety Data

• Hazardous Substances Data: 120157-60-0(Hazardous Substances Data)

Usage

General Description

2,3-O-(3-PENTYLIDENE)-D-GLYCERALDEHYDE is a chemical compound that consists of a pentylidene group attached to the 2 and 3 positions of D-glyceraldehyde. It is a derivative of glyceraldehyde and is commonly used in organic chemistry as a building block for the synthesis of various other chemical compounds. 2,3-O-(3-PENTYLIDENE)-D-GLYCERALDEHYDE is also used as an intermediate in the production of pharmaceuticals and agrochemicals. It has potential applications in the development of new drugs and in the field of chemical synthesis. Its unique structure and reactivity make it a valuable tool for the creation of complex organic molecules.

InChI:InChI=1/C8H14O3/c1-3-8(4-2)10-6-7(5-9)11-8/h5,7H,3-4,6H2,1-2H3/t7-/m0/s1

Upstream product

• 120157-59-7 1,2:5,6-di-O-(3-pentylidene)-D-mannitol 

Downstream Products

• 1612767-74-4 (S)-1-((R)-2,2-diethyl-1,3-dioxolan-4-yl)prop-2-ynyl 4-methylbenzenesulfonate 
• 152998-16-8 tert-Butyl-[(S)-3-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-3-methoxy-2,2-dimethyl-propoxy]-diphenyl-silane 
• 227299-33-4 Acetic acid (S)-2-(tert-butyl-dimethyl-silanyloxy)-3-((S)-2,2-diethyl-[1,3]dioxolan-4-yl)-1-phenylsulfanyl-but-3-enyl ester 
• 227299-32-3 [(S)-1-Benzenesulfinylmethyl-2-((S)-2,2-diethyl-[1,3]dioxolan-4-yl)-allyloxy]-tert-butyl-dimethyl-silane 
• 227299-40-3 tert-Butyl-[(S)-2-((S)-2,2-diethyl-[1,3]dioxolan-4-yl)-1-phenylsulfanylmethyl-allyloxy]-dimethyl-silane 
• 228243-80-9 (1S,2S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-3-phenylsulfanyl-propan-1-ol 
• 228243-86-5 (S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-3-phenylsulfanyl-propan-1-one 
• 227299-31-2 (S)-3-((S)-2,2-Diethyl-[1,3]dioxolan-4-yl)-1-phenylsulfanyl-but-3-en-2-ol 
• 228243-79-6 (1R,2S)-1-((R)-2,2-Diethyl-[1,3]dioxolan-4-yl)-3-phenylsulfanyl-propane-1,2-diol 
• 207302-95-2 (3R,4R,5R,6S)-5-Bromo-6-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-3-methoxy-4-methyl-tetrahydro-pyran-2-one 
• 207302-96-3 (3R,4S,5S)-5-{[(1S)-3,3-diethyl-2,4-dioxolanyl]bromomethyl}-3-methoxy-4-methyloxolan-2-one 
• 207303-18-2 (1S,2S,3R)-1-{[(1S)-3,3-diethyl-2,4-dioxolanyl]methyl}-3-methoxy-1-[(4-methoxyphenyl)methoxy]-2-methyl-4-(1,1,2,2-tetramethyl-1-silapropoxy)butane 
• 207303-05-7 (4R,5S,6S)-methyl 7-[(1S)-3,3-diethyl-2,4-dioxolanyl]-4-methoxy-6-[(4-methoxyphenyl)methoxy]-3,5-dimethylhept-2-enoate 

Relevant articles and documents

New approach for the stereoselective synthesis of (+)-epi-cytoxazone

The stereoselective total synthesis of (+)-epi-cytoxazone was performed satisfactorily in 8 steps, in 17percent overall yield, via a novel route from 2,3-O-(3-pentylidene)-(R)-glyceraldehyde. The bulky group alkene-ketal allowed intramolecular control of

Synthetic studies toward amphidinolide A: Synthesis of fully functionalized subunits

A retrosynthetic breakdown of amphidinolide A affords four fragments A- D and illustrates the main synthetic challenges of this molecule. A concise stereoselective synthesis of the four appropriately functionalized subtargets is described.