227299-40-3

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 227299-31-2 (S)-3-((S)-2,2-Diethyl-[1,3]dioxolan-4-yl)-1-phenylsulfanyl-but-3-en-2-ol 
• 19493-09-5 Methylenetriphenylphosphorane 
• 228243-86-5 (S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-3-phenylsulfanyl-propan-1-one 
• 227299-25-4 (E)-3-((S)-2,2-Diethyl-[1,3]dioxolan-4-yl)-prop-2-en-1-ol 
• 227299-29-8 ((R)-2,2-Diethyl-[1,3]dioxolan-4-yl)-(R)-oxiranyl-methanone 
• 227299-26-5 [(2S,3R)-3-((R)-2,2-Diethyl-[1,3]dioxolan-4-yl)-oxiranyl]-methanol 
• 227299-28-7 (R)-((R)-2,2-Diethyl-[1,3]dioxolan-4-yl)-(R)-oxiranyl-methanol 
• 227299-30-1 (S)-2,2-Diethyl-4-((S)-1-oxiranyl-vinyl)-[1,3]dioxolane 
• 478131-72-5 ethyl (R)-E-4,5-O-(3-pentylidene)-4,5-dihydroxy-2-pentenoate 
• 227299-27-6 (1R,2S)-3-tert-Butylsulfanyl-1-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-propane-1,2-diol 
• 228243-79-6 (1R,2S)-1-((R)-2,2-Diethyl-[1,3]dioxolan-4-yl)-3-phenylsulfanyl-propane-1,2-diol 
• 228243-80-9 (1S,2S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-3-phenylsulfanyl-propan-1-ol 
• 120157-60-0 (R)-2,2-diethyl-1,3-dioxolane-4-carboxaldehyde 

Downstream Products

• 227299-33-4 Acetic acid (S)-2-(tert-butyl-dimethyl-silanyloxy)-3-((S)-2,2-diethyl-[1,3]dioxolan-4-yl)-1-phenylsulfanyl-but-3-enyl ester 
• 227299-32-3 [(S)-1-Benzenesulfinylmethyl-2-((S)-2,2-diethyl-[1,3]dioxolan-4-yl)-allyloxy]-tert-butyl-dimethyl-silane 

Relevant academic research and scientific papers

Synthetic studies toward amphidinolide A: Synthesis of fully functionalized subunits

A retrosynthetic breakdown of amphidinolide A affords four fragments A- D and illustrates the main synthetic challenges of this molecule. A concise stereoselective synthesis of the four appropriately functionalized subtargets is described.