120166-53-2Relevant academic research and scientific papers
Tellurium in organic synthesis. Preparation of Z-vinylic cuprates from Z-vinylic tellurides and their reaction with enones and epoxides
Tucci, Fabio C.,Chieffi, Andre,Comasseto, Joao V.,Marino, Joseph P.
, p. 4975 - 4989 (2007/10/03)
Z-Vinylic tellurides, obtained with 100% stereoselectivity by the hydrotelluration of acetylenes, are easily transformed into Z-vinylic higher order cyanocuprates by reaction with preformed Me2-Cu(CN)Li2, W-Bu2Cu(CN)Lisub
REACTIONS OF SELENIUM AND TELLURIUM METALS WITH PHENYLACETYLENE IN THREE-PHASE CATALYTICAL SYSTEMS
Potapov, V. A.,Amosova, S. V.,Kashik, A. S.
, p. 613 - 616 (2007/10/02)
Compounds 2, 6a-d, 7, 8 were prepared in three-phase catalytical systems using selenium and tellurium metals as one phase.A radical anion chain mechanism is proposed in the reaction of tellurium metal with phenylacetylene.
