1201845-74-0

Basic information

• Product Name: [Zn(5-bromoisophthalate)(1,4-bis(imidazol-1-ylmethyl)benzene)]_n
• Synonyms: [Zn(5-bromoisophthalate)(1,4-bis(imidazol-1-ylmethyl)benzene)]_n
• CAS NO: 1201845-74-0
• Molecular Weight: 546.695
• Mol File: 1201845-74-0.mol

Chemical Properties

• CAS DataBase Reference: [Zn(5-bromoisophthalate)(1,4-bis(imidazol-1-ylmethyl)benzene)]_n(CAS DataBase Reference)
• NIST Chemistry Reference: [Zn(5-bromoisophthalate)(1,4-bis(imidazol-1-ylmethyl)benzene)]_n(1201845-74-0)
• EPA Substance Registry System: [Zn(5-bromoisophthalate)(1,4-bis(imidazol-1-ylmethyl)benzene)]_n(1201845-74-0)

Safety Data

• Hazardous Substances Data: 1201845-74-0(Hazardous Substances Data)

Upstream product

• 56643-83-5 1,4-bis(imidazol-l-yl-methyl)benzene 
• 23351-91-9 5-bromoisophthalic acid 

Relevant articles and documents

Syntheses, structures and photoluminescent properties of two zinc(II) coordination polymers based on aromatic polycarboxylate and 1,4-bis(imidazol-1-ylmethyl)benzene

Hydrothermal reaction of Zn(NO3)2·6H2O with benzene-1,2,3-tricarboxylic acid (H3BTC) or 5-bromoisophthalic acid (H2BIPA) in the presence of 1,4-bis(imidazol-1-ylmethyl)benzene (bix) produced two novel

Rapid mechanochemical protocol for isostructural polycatenated coordination polymers [M(BrIP)(BIX)] (M = Co(II), Zn(II))

Two dual ligand isostructural coordination polymers [Co(BrIP)(BIX)]n (1) and [Zn(BrIP)(BIX)]n (2), where BrIP = 5-bromoisophthalate and BIX = 1,4-bis(imidazol-1-ylmethyl)-benzene, have been efficiently synthesized by liquid assisted grinding methods. Single crystals of 1 were harvested by the solvothermal technique and phase pure 1 or 2 can be quantitatively obtained by grinding equimolar amounts of the metal nitrates and the ligands, 5-bromoisophthalic acid (H2BrIP) and 1,4-bis(imidazol-1-ylmethyl)-benzene (BIX) in the presence of a few drops of water or methanol. Use of freshly prepared Co(OH)2 or ZnO also yields the desired end products in an environmentally friendly manner along with the benign by-product water. The structure of 1 was established by single crystal X-ray diffraction studies, in addition to other physicochemical techniques. Morphological aspects of samples of 1 and 2 obtained via different protocols have also been studied.