120190-83-2Relevant academic research and scientific papers
REDUCTION OF ACROLEIN DIALKYL ACETALS WITH CrCl2. γ-ALKOXY SUBSTITUTED ALLYLIC CHROMIUM REAGENTS FOR SELECTIVE SYNTHESIS OF erythro-1,2-DIOLS.
Takai, Kazuhiko,Nitta, Kenji,Utimoto, Kiitiro
, p. 5263 - 5266 (2007/10/02)
Treatment of an aldehyde in THF at -30 deg C with a reagent derived by reduction of acrolein dialkyl acetal with CrCl2 in the presence of Me3SiI gave 1,2-erythro-3,4-butene-1,2-diol derivatives selectively.
