40575-57-3Relevant academic research and scientific papers
Cationic Polyaddition of p-Xylylene Glycol to 1,4-Bis(allenyloxy)xylene. Synthesis of Functional Polyacetal Containing Vinyl Groups in the Side-Chain
Sato, Eiichi,Yokozawa, Tsutomu,Endo, Takeshi
, p. 1113 - 1116 (1993)
Polyaddition of p-xylylene glycol to 1,4-bis(allenyloxy)xylene was examined.Hydroxy groups of the diol added to the internal double bonds of allenyloxy moieties of bis(alkoxyallene) selectively to afford polymers containing both vinyl groups in the side c
Pd-Catalyzed Hydroamination of Alkoxyallenes with Azole Heterocycles: Examples and Mechanistic Proposal
Bernar, Ivan,Fiser, Béla,Blanco-Ania, Daniel,Gómez-Bengoa, Enrique,Rutjes, Floris P. J. T.
, p. 4211 - 4214 (2017/08/23)
Palladium-catalyzed regio- and enantioselective addition of azole heterocycles to alkoxyallenes was developed (up to 92% yields and up to 94% ee). DFT calculations suggest a new Pd(0)-driven mechanistic pathway proceeding through protonation of the Pd-coo
Gold-catalyzed hydroalkoxylation of alkoxyallenes
Cui, Dong-Mei,Zheng, Zhi-Ling,Zhang, Chen
supporting information; experimental part, p. 1426 - 1427 (2009/06/28)
We report synthesis of allylic acetals via gold-catalyzed hydroalkoxylation of alkoxyallenes with alcohols containing primary and secondary alcohols in good to excellent yields under mild condition.
