120202-54-2Relevant academic research and scientific papers
The chemoenzymatic synthesis of 9-substituted 3,9-dideoxy-D-glycero-D- galacto-2-nonulosonic acids
Kong, David C. M.,Von Itzstein, Mark
, p. 323 - 329 (1997)
A series of C-6 functionalised mannosides has been synthesised. Subsequent exposure of 6-azido-6-deoxy-D-mannopyranose and 6-bromo-6-deoxy- D-mannopyranose to Neu5Ac aldolase and sodium pyruvate provided the corresponding 9-azido- and 9-bromo-3,9-dideoxy-D-glycero-D-galacto-2- nonulosonic acid, respectively.
6-AMINO-6-DEOXYHEXONOLACTAMS
Kefurt, Karel,Kefurtova, Zdenka,Jary, Jiri
, p. 1795 - 1805 (2007/10/02)
6-Azido-6-deoxy-D-mannose (III), prepared from methyl 4,6-O-benzylidene-α-D-mannopyranoside, 6-azido-6-deoxy-D-talose (XI), prepared from methyl 6-azido-2,3-O-isopropylidene-α-D-mennopyranoside (VII) via 4-keto derivative VIII, and 6-azido-6-deoxy-L-idose (XVIII), obtained from 5,6-anhydro-1,2-O-isopropylidene-β-L-idofuranose, on oxidation with bromine and subsequent reduction of the azido group afforded the corresponding 6-amino-6-deoxyhexonolactams V, XV, and XXI. 6-Amino-6-deoxyhexonic acids IV and XIV were also prepared.
