1202243-81-9Relevant academic research and scientific papers
Synthesis, spectroscopic and thermal studies of some IIB group complexes with a new N2-Schiff base ligand
Montazerozohori, Morteza,Khani, Sara,Tavakol, Hosein,Hojjati, Ahmad,Kazemi, Mostafa
, p. 122 - 127 (2011)
Synthesis, spectroscopic and thermal studies of some complexes of a new N2-Schiff base ligand of N1,N2-bis((E)-2- methyl-3-phenylallylidene)ethane-1,2-diamine (L) with a general formula of MLX2 (M = Zn(II), Cd(II) and Hg(II); X = Cl-, Br -, I-, SCN- and N3-) are described. The ligand and its complexes were characterized by elemental analysis, molar conductance, UV-vis spectra, FT-IR spectra, MS, 1H NMR and 13C NMR spectra. The conductivity measurement as well as spectral data indicated that the complexes are non-electrolyte. 1H and 13C NMR spectra have been studied in DMSO-d6 and/or CDCl3. The thermal behavior of the complexes shows weight loss by decomposition of the anions and ligand segments in the subsequent steps. Activation thermodynamic parameters of decomposition such as E*, ΔH*, ΔS* and ΔG* were calculated from TG curves.
