1202351-60-7Relevant articles and documents
Addition of sulfenic acids to monosubstituted acetylenes: A theoretical and experimental study
Aversa, Maria Chiara,Barattucci, Anna,Bonaccorsi, Paola,Contini, Alessandro
, p. 1048 - 1057 (2009)
The reaction of benzenesulfenic acid, generated in situ by thermal decomposition of 3-(phenylsulfinyl) propanenitrile, with monosubstituted acetylenes was experimentally and theoretically investigated at the DFT level using the MPW1B95 density functional.
Sulfoxidation of alkenes and alkynes with NFSI as a radical initiator and selective oxidant
Zhang, Yuexia,Wong, Zeng Rong,Wu, Xingxing,Lauw, Sherman J. L.,Huang, Xuan,Webster, Richard D.,Chi, Yonggui Robin
supporting information, p. 184 - 187 (2016/12/27)
Sulfoxides are important functional molecules. We develop a short-route (one-pot) synthesis of this class of molecules by reacting thiols with alkenes or alkynes under mild and metal-free conditions. N-Fluorobenzenesulfonimide (NFSI) is used to play dual roles: as a radical initiator for a thiol-ene/-yne reaction to form sulfide adducts, and as efficient oxidant for conversion of the sulfides formed in situ to sulfoxides. Over-oxidation of the sulfoxides to sulfones is avoided in our approach.