1202779-97-2Relevant academic research and scientific papers
Synergic synthesis of benzannulated zincabicyclic complexes, α-Zincated N ylides, through sodium-TM EDA-mediated zincation of a haloarene
Armstrong, David R.,Balloch, Liam,Clegg, William,Dale, Sophie H.,Garcia-Alvarez, Pablo,Hevia, Eva,Hogg, Loma M.,Kennedy, Alan R.,Mulvey, Robert E.,O'Hara, Charles T.
, p. 8675 - 8678 (2010/01/16)
Double role for sodium: Within a synergic sodium TM P-zincate reagent sodium mediates the direct ortho-zincation of chlorobenzene and delivers the TMEDA ligandto nucleophilically attack the benzene ring, thereby generating novel open and cyclic zinc zwitt
