120342-73-6Relevant academic research and scientific papers
Highly Stereoselective Synthesis of 1,3-Dienes through an Aryl to Vinyl 1,4-Palladium Migration/Heck Sequence
Hu, Tian-Jiao,Li, Meng-Yao,Zhao, Qian,Feng, Chen-Guo,Lin, Guo-Qiang
, p. 5871 - 5875 (2018/05/14)
An efficient aryl to vinyl 1,4-palladium migration/Heck sequence was developed for the stereoselective synthesis of 1,3-dienes. High stereoselectivity was observed not only for 1,3-dienes bearing two similar aryl groups at terminal positions, but also for
Silylative cyclopropanation of allyl phosphates with silylboronates
Shintani, Ryo,Fujie, Ryuhei,Takeda, Momotaro,Nozaki, Kyoko
, p. 6546 - 6549 (2014/06/24)
A potassium-bis(trimethylsilyl)amide-mediated cyclopropanation of allyl phosphates with silylboronates has been developed. Unlike the reported copper-catalyzed allylic substitution reactions, the nucleophile selectively attacks at the β-position of the allylic substrates under the present reaction conditions. The mechanism of this process has also been investigated, thus indicating the involvement of a silylpotassium species as the active nucleophilic component.
Expedient synthesis of fused azepine derivatives using a sequential rhodium(II)-catalyzed cyclopropanation/1-aza-Cope rearrangement of dienyltriazoles
Schultz, Erica E.,Lindsay, Vincent N. G.,Sarpong, Richmond
supporting information, p. 9904 - 9908,5 (2014/11/08)
A general method for the formation of fused dihydroazepine derivatives from 1-sulfonyl-1,2,3-triazoles bearing a tethered diene is reported. The process involves an intramolecular cyclopropanation of an α-imino rhodium(II) carbenoid, leading to a transien
3,5-dihydroxy-6,8-nonadienoic acids and derivatives as hypocholesterolemic agents
-
, (2008/06/13)
Variously substituted 3,5-dihydroxy-6,8-nonadienoic acids and esters, are blood cholesterol lowering agents and so are useful in the prevention and treatment of cardiovascular diseases such as atherosclerosis.
