120347-03-7Relevant academic research and scientific papers
Reaction of 3-phenylisoxazole with alkyllithiums
Di Nunno, Leonardo,Scilimati, Antonio,Vitale, Paola
, p. 2623 - 2630 (2005)
Alkyllithiums react with 3-phenylisoxazole giving C5-H abstraction followed either mainly by ring fragmentation to benzonitrile and ethynolate ion (in the case of t-BuLi) or (less hindered alkyllithiums: n-BuLi, EtLi, MeLi) also by formation of
ACYLAMIDATION OF ACETYLENES
Gridnev, I. D.,Balenkova, E. S.
, p. 1447 - 1451 (2007/10/02)
The reactions of phenylacetylene, 1-heptyne, and diphenylacetylene with the complexes of acetylfluoroborate with acetonitrile and with chloroacetonitrile take place regiospecifically and stereospecifically as syn-addition of the acetyl group and nitrile at the triple bond of the acetylene and lead to previously unknown Z-N-acyl-β-amino α,β-unsaturated ketones.
