120385-24-2

Basic information

• Product Name: <(4-methoxybenzyl)oxy>tributylstannyl methane
• Synonyms: <(4-methoxybenzyl)oxy>tributylstannyl methane
• CAS NO: 120385-24-2
• Molecular Weight: 441.242
• Mol File: 120385-24-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: <(4-methoxybenzyl)oxy>tributylstannyl methane(CAS DataBase Reference)
• NIST Chemistry Reference: <(4-methoxybenzyl)oxy>tributylstannyl methane(120385-24-2)
• EPA Substance Registry System: <(4-methoxybenzyl)oxy>tributylstannyl methane(120385-24-2)

Safety Data

• Hazardous Substances Data: 120385-24-2(Hazardous Substances Data)

Upstream product

• 66222-29-5 tri-n-butylstannylmethyl iodide 
• 105-13-5 4-Methoxybenzyl alcohol 
• 865-47-4 potassium tert-butylate 

Downstream Products

• 178624-62-9 1-(2-Cyclopent-1-enyl-allyloxymethyl)-4-methoxy-benzene 
• 178624-60-7 1-Cyclopent-1-enyl-2-(4-methoxy-benzyloxy)-ethanone 
• 178624-63-0 6-[1-(4-Methoxy-benzyloxymethyl)-vinyl]-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[1,3]dioxole 
• 178624-61-8 1-(2,2-Dimethyl-6,6a-dihydro-3aH-cyclopenta[1,3]dioxol-4-yl)-2-(4-methoxy-benzyloxy)-ethanone 
• 178624-71-0 4-(4-Methoxy-benzyloxymethyl)-2,3-dihydro-1H-cyclopenta[a]anthracene-6,11-dione 
• 178624-66-3 2,3-Dihydroxy-4-(4-methoxy-benzyloxymethyl)-2,3-dihydro-1H-cyclopenta[a]anthracene-6,11-dione 
• 171808-06-3 methyl (E) 6-(1,3-dihydro-6-(4-methoxybenzyloxymethyl)-7-methyl-3-oxo-4-p-toluenesulfonyloxyisobenzofuran-5-yl)-4-methyl-4-hexenoate 
• 20574-98-5 4-(p-methoxyphenyl)but-1-ene 
• 1315612-74-8 C₅₀H₆₂O₈Si₂ 
• 142719-10-6 2-hydroxy-2-phenylethyl p-methoxybenzyl ether 
• 1196801-46-3 C₄₇H₇₆O₆Si₃ 
• 1033333-47-9 C₃₈H₅₂O₆Si 
• 1033333-25-3 C₃₂H₃₈O₆ 
• 1033333-49-1 C₃₂H₃₈O₆ 

Relevant articles and documents

Carbenium ion formation by fragmentation of electrochemically generated oxonium ions

Fragmentation of electrochemically generated oxonium ions can be exploited to form carbenium ions at a low oxidation potential in the presence of a nucleophile. The application of this concept is demonstrated for the allylation of carbenium ions generated by the anodic oxidation of stannylmethylethers.

Synthesis of (alkoxymethyl)zirconocene chlorides: Stereochemistry of carbon-carbon bond formation in a zirconocene-Wittig rearrangement

A series of (alkoxymethyl)zirconocene chlorides (1, Cp2Zr(Cl)CH2OR, Cp = ν5-C5H5) has been prepared by treatment of Cp2ZrCl2 with (alkoxymethyl)lithium reagents. Compound 1c, Cp2Zr(Cl)CH2OCH2C6H5, crystallizes in the orthorhombic space group Pbca, with a = 15.417 (9) A?, b = 18.249 (9) A?, c = 11.746 (8) A?, and Z = 8. The X-ray crystal structure shows that the alkoxymethyl ligand is ν2, with a significant Zr-O interaction. Compounds 1 with R = benzyl or substituted benzyl undergo a Wittig rearrangement when heated to give products 3 (Cp2Zr(Cl)OCH2R). The activation parameters that were determined for the transformation, the effects of substituents on the rate of the reaction, the identity of the reaction's side products, and the retention of configuration at the benzylic carbon are all consistent with the formation of a short-lived radical pair intermediate.