120385-24-2

Upstream product

• 865-47-4 potassium tert-butylate 
• 66222-29-5 tri-n-butylstannylmethyl iodide 
• 105-13-5 4-Methoxybenzyl alcohol 

Downstream Products

• 178624-58-3 1-Cyclopent-1-enyl-2-(4-methoxy-benzyloxy)-ethanol 
• 178624-59-4 1-(2,2-Dimethyl-6,6a-dihydro-3aH-cyclopenta[1,3]dioxol-4-yl)-2-(4-methoxy-benzyloxy)-ethanol 
• 171808-06-3 methyl (E) 6-(1,3-dihydro-6-(4-methoxybenzyloxymethyl)-7-methyl-3-oxo-4-p-toluenesulfonyloxyisobenzofuran-5-yl)-4-methyl-4-hexenoate 
• 1033333-25-3 C₃₂H₃₈O₆ 
• 1033333-49-1 C₃₂H₃₈O₆ 
• 1033333-47-9 C₃₈H₅₂O₆Si 
• 1196801-46-3 C₄₇H₇₆O₆Si₃ 
• 142719-10-6 2-hydroxy-2-phenylethyl p-methoxybenzyl ether 
• 20574-98-5 4-(p-methoxyphenyl)but-1-ene 
• 1315612-74-8 C₅₀H₆₂O₈Si₂ 

Relevant academic research and scientific papers

Carbenium ion formation by fragmentation of electrochemically generated oxonium ions

Fragmentation of electrochemically generated oxonium ions can be exploited to form carbenium ions at a low oxidation potential in the presence of a nucleophile. The application of this concept is demonstrated for the allylation of carbenium ions generated by the anodic oxidation of stannylmethylethers.

Total synthesis of avermectins, part 1. Enantioselective synthesis of the southern part using a sequential Dieckmann-free radical cyclization approach

A synthesis od the C1-C9 southern moiety of avermectins has been carried out in 13 steps using an asymmetric epoxidation reaction as the only source of optical activity.Starting from 6-methylhept-5-en-2-one and tetrahydropyranyl prop

Synthesis of (alkoxymethyl)zirconocene chlorides: Stereochemistry of carbon-carbon bond formation in a zirconocene-Wittig rearrangement

A series of (alkoxymethyl)zirconocene chlorides (1, Cp2Zr(Cl)CH2OR, Cp = ν5-C5H5) has been prepared by treatment of Cp2ZrCl2 with (alkoxymethyl)lithium reagents. Compound 1c, Cp2Zr(Cl)CH2OCH2C6H5, crystallizes in the orthorhombic space group Pbca, with a = 15.417 (9) A?, b = 18.249 (9) A?, c = 11.746 (8) A?, and Z = 8. The X-ray crystal structure shows that the alkoxymethyl ligand is ν2, with a significant Zr-O interaction. Compounds 1 with R = benzyl or substituted benzyl undergo a Wittig rearrangement when heated to give products 3 (Cp2Zr(Cl)OCH2R). The activation parameters that were determined for the transformation, the effects of substituents on the rate of the reaction, the identity of the reaction's side products, and the retention of configuration at the benzylic carbon are all consistent with the formation of a short-lived radical pair intermediate.