120410-14-2

Upstream product

• 120410-08-4 (R)-[(1R,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-1-methyl-2-methylene-cyclopentyl]-((R)-5-isopropenyl-2-methyl-cyclopent-1-enyl)-methanol 
• 120410-09-5 (S)-2-((R)-2-{(R)-[(1R,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-1-methyl-2-methylene-cyclopentyl]-trimethylsilanyloxy-methyl}-3-methyl-cyclopent-2-enyl)-propionaldehyde 
• 120410-10-8 (R)-2-((R)-2-{(R)-[(1R,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-1-methyl-2-methylene-cyclopentyl]-trimethylsilanyloxy-methyl}-3-methyl-cyclopent-2-enyl)-propionaldehyde 
• 38231-11-7 (5S)-1-formyl-2-methyl-5-(1-methylethenyl)-1-cyclopentene 
• 117152-37-1 (R)-2-((S)-2-{(S)-[(1R,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-1-methyl-2-methylene-cyclopentyl]-trimethylsilanyloxy-methyl}-3-methyl-cyclopent-2-enyl)-propionaldehyde 
• 117152-35-9 (S)-[(1R,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-1-methyl-2-methylene-cyclopentyl]-((S)-5-isopropenyl-2-methyl-cyclopent-1-enyl)-methanol 
• 93178-06-4 (3S,8R)-9-benzyloxy-7-chloroirid-1-ene 
• 3865-09-6 (R)-2-methyl-5-(prop-1-en-2-yl)cyclopent-1-ene-1-carbaldehyde 
• 120410-15-3 [(R)-[(1R,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-1-methyl-2-methylene-cyclopentyl]-((R)-5-isopropenyl-2-methyl-cyclopent-1-enyl)-methoxy]-trimethyl-silane 
• 75-77-4 chloro-trimethyl-silane 
• 120354-76-9 (R)-2-((R)-2-{(R)-[(1R,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-1-methyl-2-methylene-cyclopentyl]-hydroxy-methyl}-3-methyl-cyclopent-2-enyl)-propionaldehyde 
• 117152-36-0 [(S)-[(1R,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-1-methyl-2-methylene-cyclopentyl]-((S)-5-isopropenyl-2-methyl-cyclopent-1-enyl)-methoxy]-trimethyl-silane 
• 117182-68-0 (S)-2-((S)-2-{(S)-[(1R,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-1-methyl-2-methylene-cyclopentyl]-trimethylsilanyloxy-methyl}-3-methyl-cyclopent-2-enyl)-propionaldehyde 
• 120410-16-4 (S)-2-((R)-2-{(R)-[(1R,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-1-methyl-2-methylene-cyclopentyl]-trimethylsilanyloxy-methyl}-3-methyl-cyclopent-2-enyl)-propan-1-ol 

Downstream Products

• 120410-18-6 {(3S,4R,4aR,7S)-7-[(S)-5-((R)-2-Benzyloxy-1-methyl-ethyl)-2-methyl-cyclopent-1-enylmethyl]-4,7-dimethyl-3,4,4a,5,6,7-hexahydro-cyclopenta[c]pyran-3-yloxy}-trimethyl-silane 
• 120410-12-0 {(3R,4R,4aR,7S)-7-[(S)-5-((R)-2-Benzyloxy-1-methyl-ethyl)-2-methyl-cyclopent-1-enylmethyl]-4,7-dimethyl-3,4,4a,5,6,7-hexahydro-cyclopenta[c]pyran-3-yloxy}-trimethyl-silane 

Relevant academic research and scientific papers

Synthetic Photochemistry. Part 44. Total Synthesis of Ceroplastol II and Albolic Acid, 5-8-5-Membered Tricyclic Sesterterpenoid Insect Wax Constituents, via Stereocontrolled Silyloxy-Cope Rearrangement with a Normally Disfavoured Transition State

To a 1,5-diene, prepared by CrCl2-mediated condensation of two iridoid synthons, was appended a lactol moiety, which was subjected to a stereocontrolled silyloxy-Cope rearrangement to give, via a normally disfavoured boat transition geometry, a thermolysa

Total Synthesis of Albolic Acid and Ceroplastol II, 5-8-5-Membered Tricyclic Insect Sesterterpenoids, via a Lactol-Regulated Silyloxy-Cope Rearrangement

Optically active albolic acid and ceroplastol II, 5-8-5-membered tricyclic sesterterpenoids, were stereoselectively synthesised from two C10 synthons (iridoids) via CrCl2-condensation, lactol-regulated silyloxy-Cope rearrangement with a normally disfavour

Total Synthesis of Dictymal, a B-seco-Dictymenoid Aldehyde from an Alga, Dictyota dichotoma

A B-seco-dictymenoid aldehyde, dictymal, was synthesized from two optically active iridoid synthons; the required ring system was constructed by lactol-regulated Cope rearrangement and stereoselective Li-tert-BuOH-in-HMPA reduction of the tetrasubstituted