1204595-67-4Relevant academic research and scientific papers
Studies towards the total synthesis of (+)-13-deoxytedanolide: Stereoselective synthesis of C1-C9 and C9-C17 fragments
Yadav, Jhillu Singh,Chinnam, Vijaya Vardhan,Das, Saibal
, p. 728 - 731 (2016)
A facile and stereoselective synthesis of C1-C9 and C9-C17 fragments of (+)-13-deoxytedanolide and studies towards the synthesis of (+)-13-deoxytedanolide was accomplished in 20 linear steps. The key transformations of fragment 6 are Sharpless asymmetric dihydroxylation and preparation of terminal olefin from primary alcohol utilising organo selenium reaction. The key transformations of fragment 7 are from Sharpless epoxidation and Crimmin's syn aldol chemistry.
Stereoselective synthesis of the C1-C11 tetrahydropyran core unit of (+)-zincophorin
Sabitha, Gowravaram,Srinivas, Rangavajjula,Yadav, Jhillu S.
experimental part, p. 1484 - 1488 (2011/06/11)
Synthesis of the C1-C11 tetrahydropyran core unit of (+)-zincophorin using a desymmetrization strategy is reported. Horner-Wadsworth-Emmons (HWE) and Mitsunobu cyclization reactions are the key transformations. Georg Thieme Verlag Stuttgart - New York.
Total synthesis of pteridic acid A
Yadav,Rajender,Gangadhara Rao
supporting information; experimental part, p. 348 - 350 (2010/03/25)
(Figure presented) A convergent approach to the total synthesis of pteridic acid A, having potent plant growth regulator activity, Is described. Key steps include the desymmetrization of bicyclic olefin with Brown's chiral hydroboration, acid-mediated spiroketalization, and zirconium-catalyzed ethylmagnesation protocol to Install the ethyl stereocenter at C14.
