120533-54-2

Upstream product

• 3882-46-0 5H-indeno[1,2-b]pyridin-5-one 
• 98-86-2 acetophenone 
• 87446-06-8 9-Phenylethynyl-4-azafluoren-9-ol 
• 536-74-3 phenylacetylene 
• 107-13-1 acrylonitrile 
• 1001919-90-9 9-phenacyl-4-azafluorene 

Downstream Products

• 91459-30-2 3'-Phenylspiro(4-azafluorene-9,5'-pyrazol-2'-ine) 
• 120560-93-2 9-(1,2-dibenzoylethylidene)-4-azafluorene 
• 148711-80-2 9-(1',2'-dibenzoylethylidene)-4-azafluorene hydrochloride 
• 180587-13-7 9-bromo-9-(α-bromophenacyl)-4-azafluorene 
• 121400-50-8 7-phenylpyrazolo<4,3-l>-4-azaphenathrene 
• 121400-49-5 5-phenylpyrazolo<3,4-l>-4-azaphenathrene 
• 91459-29-9 3'-Phenylethynylspiro<4-azafluorene-9,1'-indene> 
• 120533-57-5 9-(α-ethoxycarbonylphenacylidene)-4-azafluorene 
• 91459-28-8 3'-Hydroxy-3'-phenylethynylspiro<4-azafluorene-9,1'-indan> 
• 120533-56-4 9-hydroxy-9-(1'-hydroxy-1',2'-dibenzoylethyl-1')-4-azafluorene 
• 1001919-90-9 9-phenacyl-4-azafluorene 

Relevant academic research and scientific papers

Cyanoethylation of substituted 4-azafluorenes. Synthesis of spiro-[4-azafluorene-9-cyclopentenes]

Cyanoethylation of 9-phenacyl(β-hydroxy-β-phenylethyl-, or acetamido)-4-azafluorenes under conditions of the Michael reaction occurs regioselectively at position 9. 1-Amino-4-azafluorene under these conditions forms 1-[N,N-di-(β-cyanoethyl)amino)]-(9-β-cy

PREPARATION OF 9-PHENYLETHYNYL-4-AZAFLUOREN-9-OL AND 9-PHENACYLIDENE-4-AZAFLUORENE AND THEIR CONVERSION TO SPIRO COMPOUNDS

9-Phenylethynyl-4-azafluoren-9-ol, which was obtained from 4-azafluorenone and phenylethynylmagnesium iodide, was used in syntheses of isomeric 9-phenacylidene-4-azafluorenes and spiro compounds with indene, indan, and pyrazoline fragments.It is assumed that conversion of 9-phenacylidene derivatives to spiro compounds takes place via intramolecular substitution.