1206101-75-8Relevant academic research and scientific papers
Syntheses and anion binding capabilities of bis(diarylboryl) ferrocenes and related systems
Kelly, Michael J.,Broomsgrove, Alexander E.J.,Morgan, Ian R.,Siewert, Inke,Fitzpatrick, Philip,Smart, Jessica,Vidovic, Dragoslav,Aldridge, Simon
, p. 2674 - 2684 (2013/06/26)
Isomeric diborylated ferrocenes featuring 1,1′-, 1,2-, and 1,3-substitution patterns have been targeted via a combination of electrophilic aromatic substitution and directed ortho-lithiation protocols. While none of these systems are competent for the Lewis acid chelation of fluoride, related systems featuring a mixed B/Si acceptor set capture 1 equiv of fluoride via a Si-F-B bridging motif.
Anion recognition by highly sterically encumbered 1,2-diborylferrocenes
Morgan, Ian R.,Broomsgrove, Alexander E. J.,Fitzpatrick, Philip,Vidovic, Dragoslav,Thompson, Amber L.,Fallis, Ian A.,Aldridge, Simon
, p. 4762 - 4765 (2010/12/25)
The syntheses and structural characterization of sterically encumbered 1,2-diborylferrocenes are reported, together with an investigation of their anion recognition capabilities with respect to fluoride and cyanide. Surprisingly, 1,2-fc(BMes2)
Facile syntheses of dissymmetric ferrocene-functionalized Lewis acids and acid-base pairs
Morgan, Ian R.,Di Paolo, Angela,Vidovic, Dragoslav,Fallis, Ian A.,Aldridge, Simon
, p. 7288 - 7290 (2010/06/14)
A facile synthetic approach is reported for the synthesis of dissymmetric 1,2-ferrocenediyl Lewis acids and mixed acid-base pairs including the first example of a 1-phosphino-2-borylferrocene; the use of non-racemic electrophiles allows for the isolation
