436-59-9

Basic information

• Product Name: DIMESITYLBORON FLUORIDE
• Synonyms: DIMESITYLBORON FLUORIDE;Dimesitylfluoroborane;fluorodiMesitylborane;Borane,fluorobis(2,4,6-triMethylphenyl)-;DiMesitylboron fluoride 90%
• CAS NO: 436-59-9
• Molecular Formula: C₁₈H₂₂BF
• Molecular Weight: 268.18
• Product Categories: Boronic Acids and Derivatives;Organometallic Reagents;Others
• Mol File: 436-59-9.mol
• Article Data: 10

Chemical Properties

• Melting Point: 69-72 °C(lit.)
• Boiling Point: 129°C/0.5mmHg(lit.)
• Flash Point: 174.1 °C
• Appearance: /
• Density: 0.98 g/cm³
• Vapor Pressure: 3.59E-05mmHg at 25°C
• Refractive Index: 1.518
• Solubility: soluble in Acetone,Ether
• CAS DataBase Reference: DIMESITYLBORON FLUORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: DIMESITYLBORON FLUORIDE(436-59-9)
• EPA Substance Registry System: DIMESITYLBORON FLUORIDE(436-59-9)

Safety Data

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-28-36/37/39-45
• RIDADR: UN 3261 8/PG 2
• WGK Germany: 3
• HazardClass: 8
• PackingGroup: III
• Hazardous Substances Data: 436-59-9(Hazardous Substances Data)

Usage

General Description

Dimesitylboron fluoride is a chemical compound primarily used as a reagent in organic synthesis. As a boron compound, it exhibits unique properties that make it effective in several organic transformation processes, such as the conversion of aldehydes and ketones to alkenes. The compound is often used as a lewis acid catalyst due to its favorable decision for 1,2- versus 1,4-additions in carbonyl condensation reactions. It is noted for its stability and ease of handling compared to other boron-based reagents. Its chemical formula is C18H18BF and is also known as BDMS and Fluoro-dimesitylborane.

InChI:InChI=1/C18H22BF/c1-11-7-13(3)17(14(4)8-11)19(20)18-15(5)9-12(2)10-16(18)6/h7-10H,1-6H3

Upstream product

• 109-63-7 trifluoroborane diethyl ether 
• 2633-66-1 2-mesitylmagnesium bromide 
• 109-63-7 boron trifluoride diethyl etherate 
• 576-83-0 2,4,6-trimethylphenyl bromide 

Downstream Products

• 42931-60-2 {2,4,6-(CH₃)3C₆H₂}2B-N(CH₃)(1-C₁₀H₇) 
• 42931-56-6 N-(dimesitylboryl)-N-phenylbenzenamine 
• 50418-09-2 9-(dimesitylboryl)anthracene 
• 50418-12-7 Dimesityl-9-(10-methoxyanthryl)boran 
• 50623-74-0 dimesityl(o-tolyl)borane 
• 440361-72-8 (diphenylmethylsilyl)dimesitylborane 
• 440361-73-9 (diphenyl-tert-butylsilyl)dimesitylborane 
• 919364-26-4 1,4-bis(dimesitylboryl)-2,5-bis(trimethylsilylethynyl)benzene 

Relevant articles and documents

Bithiophene-Cored, mono-, bis-, and tris-(Trimethylammonium)-Substituted, bis-Triarylborane Chromophores: Effect of the Number and Position of Charges on Cell Imaging and DNA/RNA Sensing

The synthesis, photophysical, and electrochemical properties of selectively mono-, bis- and tris-dimethylamino- and trimethylammonium-substituted bis-triarylborane bithiophene chromophores are presented along with the water solubility and singlet oxygen s

Bonding in Barium Boryloxides, Siloxides, Phenoxides and Silazides: A Comparison with the Lighter Alkaline Earths

Barium complexes ligated by bulky boryloxides [OBR2]? (where R=CH(SiMe3)2, 2,4,6-iPr3-C6H2 or 2,4,6-(CF3)3-C6H2), siloxide

Compound, display panel and display apparatus

The invention provides a compound with a D-pi-A type chemical structure. The compound has the structure shown in the formula I, wherein D1 and D2 represent electron-donating groups, m, n, p and q areindependently selected from 0, 1 or 2, X and Y are indep