120621-46-7Relevant academic research and scientific papers
Atom-Economic Silver-Catalyzed Difunctionalization of the Isocyano Group with Cyclic Oximes: Towards Pyrimidinediones
Liang, Hong-Wen,Yang, Zhen,Jiang, Kun,Ye, Ying,Wei, Ye
supporting information, p. 5720 - 5724 (2018/04/25)
An unprecedented silver-catalyzed difunctionalization of the isocyano group with cyclic oximes is described. This method allows efficient and atom-economic assembly of a vast array of structurally novel and interesting pyrimidinediones, and tolerates a range of functionalities. The resulting products can be easily converted into some useful compounds. Furthermore, the method can also be applied for the late-stage modification of a few biologically active molecules.
3,4-Disubstituted Isoxazolin-5-ones by Sodium Borohydride Reduction of 4-Arylmethylene- and 4-Alkylideneisoxazol-5(4H)-ones
Beccalli, Egle M.,Benincori, Tiziana,Marchesini, Alessandro
, p. 886 - 888 (2007/10/02)
Reduction of 4-arylmethylene- and 4-alkylidenisoxazol-5(4H)-ones with sodium borohydride affords the corresponding 3,4-disubstituted isoxazol-5(4H)-ones.
