120666-38-8Relevant academic research and scientific papers
A sandwich-shaped M3L2 zinc(II) complex containing 1,3,5-tris(dimethyl(pyridin-3-yl)silyl)benzene: Selective photoluminescence recognition of dIIodomethane
Lee, Sangseok,Lee, Haeri,Jung, Ok-Sang
, p. 5843 - 5847 (2017)
Self-assembly of Zn(ClO4)2 with 1,3,5-tris(dimethyl(pyridin-3-yl)silyl)benzene (L) as a new C3-symmetric tridentate N-donor gives rise to a discrete sandwich-shaped M3L2 architecture, [Zn3(
Nanosized starlike molecules. Synthesis and optical properties of tris- and tetrakis[oligo(disilanylenebithienylene)dimethylsilyl]benzene
Naka, Akinobu,Matsumoto, Yoshiaki,Itano, Tatsuya,Hasegawa, Kei,Shimamura, Tomoaki,Ohshita, Joji,Kunai, Atsutaka,Takeuchi, Takae,Ishikawa, Mitsuo
experimental part, p. 346 - 352 (2009/04/13)
The syntheses of two types of starlike molecules with the arms that extend to three and four directions have been reported. The molecules with the arms consisting of a regular alternating arrangement of a silicon-silicon bond and bithienylene unit that ex
Siloxa-bridged-cyclophanes featuring benzene, thiophene and pyridine units
Moores, Audrey,Defieber, Christian,Mezailles, Nicolas,Maigrot, Nicole,Ricard, Louis,Le Floch, Pascal
, p. 994 - 999 (2007/10/03)
Two octamethyldisiloxa-bridged [3.3]cyclophanes (1 and 2) and a dodecamethyltrissiloxa-bridged [3.3.3]-cage compound (3) were prepared by hydrolysis of the chlorosilyl monomers. This general route was also employed for the preparation of two octamethyldisiloxa-bridged [3.3]heterophanes featuring two thiophene (14) or pyridine (17) moities.
Polycylopentadienyls: synthesis of arylsilylcyclopentadienyl compounds and their η5-complexes with tungsten
Plenio, Herbert
, p. 21 - 28 (2007/10/02)
A general route to arylsilylcyclopentadienyl compounds starting from 1,4-C6H4Br2, 2,6-C5NH3Br2 and 1,3,5-C6H3Br3 is described.The aryl bromides were treated with Mg/ClSiMe2H to give the aryldimethylsilanes 1,4-C6H4(SiMe2H)2, 2,6-C5NH3(SiMe2H)2, and 1,3,5-C6H3(SiMe2H)3 which after reaction with Cl2 or Br2 yielded the aryldimethylsilyl halides 1,4-C6H4(SiMe2Br)2, 2,6-C5NH3(SiMe2Br)2, 1,3,5-C6H3(SiMe2X)3 (X=Br or Cl) in excellent yields.The halide can be replaced by various cyclopentadienides to give aryldimethylsilylcyclopentadienes of the general type 1,4-C6H4(SiMe2Cp)2 and 1,3,5-C6H3(SiMe2Cp)3 (Cp=C5H5 (8,11), C5H3(t-C4H9)2 (9, 12), C5HMe4 (10, 13)).Compounds C6H5(SiMe2(C5H5)), 1,4-C6H4(SiMe2(C5H5))2 (8) and 1,3,5-C6H3(SiMe2(C5H5))3 (11) were in turn treated with NaH, (MeCN)3W(CO)3, and MeI to give the η5-bound complexes C6H5(SiMe2(C5H4)W(CO)3Me) (14), 1,4-C6H4(SiMe2(C5H4)W(CO)3Me)2 (15), 1,3,5-C6H3(SiMe2(C5H4)W(CO)3Me)3 (16), which contain up to three half-sandwich units within one molecule.
