120686-98-8Relevant academic research and scientific papers
Synthesis of protected enantiopure erythrulose derivatives
Marco, J. Alberto,Carda, Miguel,Gonzalez, Florenci,Rodriguez, Santiago,Murga, Juan
, p. 1801 - 1810 (2007/10/03)
D- and L-Erythrulose derivatives 2-6 bearing protective O-silyl and O-benzyl groups in various positions were synthesized in enantiopure form from L-ascorbic acid, D-isoascorbic acid, and D-glucose. VCH Verlagsgesellschaft mbH, 1996.
Chiral Lactols, VIII - A Way for the Asymmetric Induction in the Formation of Sugars
Noe, Christian R.,Knollmueller, Max,Ettmayer, Peter
, p. 637 - 644 (2007/10/02)
The substituted glycol aldehyde 4 which bears an enantiomerically pure acetal-type protective group exhibiting the configuration of an α-L-sugar at the acetal centre is subjected to aldolization under basic conditions.The resulting products are reduced and characterized by comparison with reference compounds of known absolute configuration.L-Sugars are formed preferentially with L-erythrose being the main product.
