120713-37-3Relevant articles and documents
Distal Functional Group Migration for Visible-light Induced Carbo-difluoroalkylation/monofluoroalkylation of Unactivated Alkenes
Yu, Jiajia,Wang, Dongping,Xu, Yan,Wu, Zhen,Zhu, Chen
supporting information, p. 744 - 750 (2017/12/26)
A general and practical protocol for elusive carbo-difluoroalkylation/ monofluoroalkylation of unactivated alkenes based on the distal functional group migration is described. A portfolio of functional groups including heteroaryl, imino, formyl, and alkynyl groups showcase the migratory aptitude. In combination with visible-light photocatalysis, a broad range of di- and mono-fluorinated alkyl ketones are readily obtained in synthetically useful yields under mild reaction conditions. (Figure presented.).
Fungicidal and plant growth-regulating azolyl-tetrahydropyran derivatives
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, (2008/06/13)
Fungicidal and plant growth-regulating azolyltetrahydropyran derivatives of the formula STR1 in which R represents hydrogen, alkyl or acyl, R1 represents optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl and X represents nitrogen or a CH group, and addition products thereof with acids and metal salts. Intermediates of the formula STR2 are also new.