1207202-33-2Relevant academic research and scientific papers
Preparation of functionalized aryl iron(II) compounds and a nickel-catalyzed cross-coupling with alkyl halides
Wunderlich, Stefan H.,Knochel, Paul
supporting information; experimental part, p. 9717 - 9720 (2010/04/28)
The ortho-ferration of functionalized arenes using tmp2Fe-2MgCl2-4 LiCl furnishes the corresponding diorgano Fell reagents at 258C in high yields. These reagents undergo cross-coupling reactions in the presence of 4-fluorostyrene to give various alkylated arenes. It turned out that Nill impurities present in commercial FeCl2 (98% pure] catalyzed this alkyl-aryl cross-coupling reaction.
