120726-19-4

Basic information

• Product Name: Me₃SnCH(OEt)CH₂PPh₂
• CAS NO: 120726-19-4
• Molecular Weight: 421.107
• Mol File: 120726-19-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Me₃SnCH(OEt)CH₂PPh₂(CAS DataBase Reference)
• NIST Chemistry Reference: Me₃SnCH(OEt)CH₂PPh₂(120726-19-4)
• EPA Substance Registry System: Me₃SnCH(OEt)CH₂PPh₂(120726-19-4)

Safety Data

• Hazardous Substances Data: 120726-19-4(Hazardous Substances Data)

Upstream product

• 112713-84-5 trimethyl(1-ethoxylvinyl)tin 
• 829-85-6 diphenylphosphane 

Downstream Products

• 120726-24-1 (β-trimethylstannyl)CH(OEt)CH2(diphenylphosphine oxide) 

Relevant articles and documents

Stannylated phosphines. I. Preparation of (β-trimethylstannyl)alkyldiphenylphosphines

(β-Trimethylstannyl)alkyldiphenylphosphines can be readily prepared by addition of diphenylphosphine to the corresponding vinyltrimethyltin Me3SnCR=CH2 under free radical conditions.In contrast, free radical hydrostannation of the corresponding phosphines Ph2PCR=CH2 is a more complex process, and is apparently of little synthetic value.The title compound can be easily oxidised by potassium permanganate to give the corresponding phosphine oxides in good yields.Hydrostannation of model alkynyldiphenylphosphines (RCCPPh2, R=H, Me3Sn) occurs regiospecifically.