1207289-05-1

Basic information

• Product Name: methyl 2-(allylthio)benzoate
• Synonyms: methyl 2-(allylthio)benzoate
• CAS NO: 1207289-05-1
• Molecular Weight: 208.281
• Mol File: 1207289-05-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: methyl 2-(allylthio)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(allylthio)benzoate(1207289-05-1)
• EPA Substance Registry System: methyl 2-(allylthio)benzoate(1207289-05-1)

Safety Data

• Hazardous Substances Data: 1207289-05-1(Hazardous Substances Data)

Upstream product

• 100-44-7 benzyl chloride 
• 4892-02-8 Methyl thiosalicylate 
• 107-05-1 3-chloroprop-1-ene 
• 106-95-6 allyl bromide 

Downstream Products

• 1515696-04-4 (R)-methyl 2-(propylsulfinyl)benzoate 
• 1515696-23-7 methyl 2-(propoxythio)benzoate 
• 1515695-96-1 methyl 2-(allylsulfinyl)benzoate 
• 131142-97-7 [2-(allylthio)phenyl]methanol 
• 1207289-08-4 3-(2-(allylthio)phenyl)propiolic acid 
• 1207289-07-3 methyl 3-(2-(allylthio)phenyl)propiolate 
• 1207289-06-2 allyl(2-(2,2-dibromovinyl)phenyl)sulfane 

Relevant articles and documents

A novel pathway for the thermolysis of N-nitrosoanthranilates using flash vacuum pyrolysis leading to 7-aminophthalides

Flash vacuum pyrolysis of methyl N-methyl-N-nitrosoanthranilate leads to elimination of nitric oxide and disproportionation of the formed N-radical to 7-(methylamino)phthalide and methyl N-methylanthranilate. This transformation was found to be a convenient, solvent-free method for the preparation of 7-(methylamino)phthalides. An alternative route through pyrolysis of N-benzyl-N-methyl anthranilates was also investigated. This journal is

The Synthesis of 5-Amino-dihydrobenzo[b]oxepines and 5-Amino-dihydrobenzo[b]azepines via Ichikawa Rearrangement and Ring-Closing Metathesis

The combination of Ichikawa's rearrangement and a ring-closing metathesis reaction of allyl carbamates is presented as a method for the preparation of 5-amino-substituted 2,5-dihydro-benzo[b]oxepines, 2,5-dihydro-benzo[b]azepines, and 2,5-dihydro-benzo[b]thiepins. It was demonstrated that the use of nonracemic allyl carbamates enables the synthesis of enantioenriched benzo-fused seven-membered heterocycles. Finally, it was shown that further functionalization of the obtained structures allows access to pharmacologically active 5-amino-substituted 2,3,4,5-tetrahydro-1-benzo[b]oxepine scaffolds.

Palladium-catalyzed intramolecular carboesterification of olefins

One catalyst three bonds: The title reaction between propiolic acids and unactivated olefins (see scheme; O red, Cl green) results in vicinal functionalization of the olefin, with the formation of new C-C and C-O bonds. Structurally complex 6,7,5-tricyclic ring systems are formed in a single step by this cascade chloropalladation and formal [3+2] cycloaddition.