1207299-54-4Relevant academic research and scientific papers
Ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium-phosphine complexes
Ishiyama, Tatsuo,Isou, Hironori,Kikuchi, Takao,Miyaura, Norio
, p. 159 - 161 (2010)
Iridium complexes generated from [Ir(OMe)(COD)]2 and tris[3,5-bis(trifluoromethyl)phenyl]phosphine efficiently catalyzed the ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron in octane at 80 °C to produce the corresponding ary
A new air-stable Si,S-chelating ligand for Ir-catalyzed directed: Ortho C-H borylation
Jiao, Jiao,Nie, Wenzheng,Song, Peidong,Li, Pengfei
supporting information, p. 355 - 359 (2021/01/29)
A new air-stable Si,S-chelating ligand has been developed and used in an iridium-catalyzed ortho C-H borylation reaction with a broad substrate scope. This study provides the first example of using a sulfur-containing ligand in the catalytic C-H borylation process. It provides a rapid, efficient, and economical method for the preparation of organoboron compounds. This journal is
