1207356-78-2Relevant academic research and scientific papers
Synthesis of Secondary Amides from Thiocarbamates
Mampuys, Pieter,Ruijter, Eelco,Orru, Romano V. A.,Maes, Bert U. W.
supporting information, p. 4235 - 4239 (2018/07/29)
The synthesis of secondary amides from readily accessible and bench-stable substituted S-phenyl thiocarbamates and Grignard reactants is reported. Oxidative workup allows recycling of the thiolate leaving group as diphenyl disulfide. Diphenyl disulfide can be transformed into S-phenyl benzenethiosulfonate, a reactant required for thiocarbamate synthesis. This amide synthesis is suitable for the preparation of challenging amides that are not or hardly accessible via classical approaches.
Process for producing 2-alkylbenzanilide
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, (2008/06/13)
2-Alkylbenzanilide is produced by reacting an alkyl 2-alkylbenzoate having the formula STR1 wherein X represents a lower alkyl group and R represents a lower alkyl group with an aniline having the formula STR2 wherein Y represents hydrogen atom, an alkoxy
