1207384-16-4

Upstream product

• 1207384-14-2 (4aS,5S,6S,8aS)-6-(benzyloxy)-5,8a-dimethyl-3-oxo-3,4,4a,5,6,7,8,8a-octahydronaphthalene-2-carbaldehyde 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 118635-66-8 (E)-5-((tert-butyldimethylsilyl)oxy)pent-2-en-1-al 
• 86462-75-1 (E)-5-(tert-butyldimethylsilanyloxy)pent-2-en-1-ol 
• 688801-64-1 (E)-methyl 5-[(tert-butyldimethylsilyl)oxy]pent-2-enoate 
• 73842-99-6 3-tert-butyldimethylsilyloxy-1-propanol 
• 105087-08-9 (1S,2S,4aS,7S,8aS)-1,4a-dimethyl-7-(prop-1-en-2-yl)decahydronaphthalen-2-ol 
• 547-26-2 (+)-7-epi-α-cyperone 
• 89922-82-7 3-(tert-butyldimethylsilanyloxy)propionaldehyde 

Downstream Products

• 1207384-17-5 C₃₂H₄₈O₅Si 

Relevant academic research and scientific papers

Anionic polycyclization entry to tricycles related to quassinoids and terpenoids: A stereocontrolled total synthesis of (+)-cassaine

A full account of our anionic polycyclization approach to access highly functionalized tricycles related to quassinoids and terpenoids from several optically active bicyclic enone systems and Nazarov reagents is presented. (+)-Carvone is the only chiral s

Versatile strategy to access tricycles related to quassinoids and triterpenes

[Chemical equaction presented] The reactivity of two new bicyclic cyclohexenones (13 and 27) with several Nazarov reagents is presented. A flexible synthetic strategy is developed and provides access to highly substituted tricycles related to quassinoids