120786-25-6

Basic information

• Product Name: <2R-(2α(R*,S*),3aα,4β,7β,7aα)>-1-<(Octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl)oxy>-3,4-bis(phenylmethoxy)-2-butanol
• CAS NO: 120786-25-6
• Molecular Weight: 480.645
• Mol File: 120786-25-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: <2R-(2α(R*,S*),3aα,4β,7β,7aα)>-1-<(Octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl)oxy>-3,4-bis(phenylmethoxy)-2-butanol(CAS DataBase Reference)
• NIST Chemistry Reference: <2R-(2α(R*,S*),3aα,4β,7β,7aα)>-1-<(Octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl)oxy>-3,4-bis(phenylmethoxy)-2-butanol(120786-25-6)
• EPA Substance Registry System: <2R-(2α(R*,S*),3aα,4β,7β,7aα)>-1-<(Octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl)oxy>-3,4-bis(phenylmethoxy)-2-butanol(120786-25-6)

Safety Data

• Hazardous Substances Data: 120786-25-6(Hazardous Substances Data)

Upstream product

• 108031-80-7 (2S,2'S-(2α,2'α,3aα,3a'α,4β,4'β,7β,7'β,7aα,7a'α))-2,2'-oxybis[octahydro-7,8,8-trimethyl-4,7-methanobenzofuran] 
• 114184-99-5 <4R-(R*,S*)>-4-<1,2-Bis(phenylmethoxy)ethyl>-2,2-dimethyl-1,3-dioxolan 

Downstream Products

• 120786-26-7 <2R-(2α(R*,S*),3aα,4β,7β,7aα)>-Octahydro-7,8,8-trimethyl-2-<2,3,4-tris(phenylmethyloxy)butoxy>-4,7-methanobenzofuran 

Relevant articles and documents

Chiral Lactols, VIII - A Way for the Asymmetric Induction in the Formation of Sugars

The substituted glycol aldehyde 4 which bears an enantiomerically pure acetal-type protective group exhibiting the configuration of an α-L-sugar at the acetal centre is subjected to aldolization under basic conditions.The resulting products are reduced and characterized by comparison with reference compounds of known absolute configuration.L-Sugars are formed preferentially with L-erythrose being the main product.