120800-97-7Relevant academic research and scientific papers
CHEMISTRY OF SILYL THIOKETONES. Part 6. SYNTHESIS OF 5-MEMBERED SILYL-HETEROCYCLES VIA 1,3-DIPOLAR CYCLOADDITION TO ARYL SILYL THIOKETONES
Bonini, Bianca F.,Maccagnani, Gaetano,Mazzanti, Germana,Abdel-lateef, Ghamel,Atwa, Achmed,et al.
, p. 47 - 57 (2007/10/02)
Aryl silyl thioketones react with 1,3-dipoles (nitriloxides, nitrilimine and nitrile ylide) to give regiospecifically silyl thiaheterocycles.These cycloadducts undergo desilylation leading either to ring fragmentation products or to the H-substituted heterocycles.
Chemistry of Silyl Thioketones. Part 4. 2,4,6-Triaryl-2,4,6-tris(trimethylsilyl)-1,3,5-trithianes from Silyl Thioketones: Crystal Structure of 2,4,6-Triphenyl-2,4,6-tris(trimethylsilyl)-1,3,5-trithiane and Stereochemistry of Desilylation with Fluoride Ion
Bonini, Bianca F.,Mazzanti, Germana,Zani, Paolo,Maccagnani, Gaetano
, p. 1499 - 1502 (2007/10/02)
Silyl thioketones are easily converted into the corresponding trimers (1,3,5-trithianes) under acidic conditions.Both the α-(cis,trans)-and the β-(cis,cis)-isomers were isolated.The β-diastereoisomers predominate over the α-form.The major isomer from the
