120814-15-5Relevant articles and documents
Adducts of ArSCl with vinyl ethers or esters as synthones in geminal alkylation
Smit, William A.,Gromov, Alexei V.,Yagodkin, Elisey A.
, p. 21 - 23 (2003)
The in situ-prepared adducts of arylsulfenyl chloride and vinyl ethers (esters) were employed as synthetic equivalents of 1,1-bis-electrophiles in the Lewis acid-promoted reaction sequence with two different carbon nucleophiles resulting in the formation of geminal bisalkylation products.
REACTION SEQUENCE ARYLSULFENYL CHLORIDE + ALKOXYALKENE-I + ALKOXYALKENE-II + ALLYLMAGNESIUM OR BORON DERIVATIVES AS A NEW METHOD FOR THE CONTROLLED SYNTHESIS OF POLYFUNCTIONAL DERIVATIVES
Smolyakova, I. P.,Smit, V. A.,Bubnov, Yu. N.,Shashkov, A. S.
, p. 981 - 987 (2007/10/02)
A new method is proposed for the controlled synthesis of polyfunctional compouds with formation of two new carbon-carbon bonds; the method is based on the following reaction sequence, which can be carried out in a single flask: addition of ArSCl to vinyl ether I, reaction of the resultant adduct with vinyl ether II in the presence of Lewis acid to form a cationic complex, and treatment of the latter with allyl derivatives of boron or magnesium.
