120818-46-4

Upstream product

• 106-44-5 p-cresol 
• 1600-27-7 mercury(II) diacetate 
• 119005-64-0 methyl onate 
• 119005-63-9 methyl onate 
• 119070-22-3 phenyl 2-deoxy-3,4,6-tris-O-(phenylmethyl)-1-thio-D-arabino-hexopyranoside 
• 91780-35-7 chloro-3,4,6-tri-O-benzyl-2-deoxy-D-glucopyranoside 
• 119068-33-6 phenyl 3,4,6-tri-O-benzyl-2-deoxy-1-sulphonyl-αβ-D-arabino-pyranoside 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 

Downstream Products

• 120818-48-6 p-tolyl 3,4,6-tri-O-benzyl-2-deoxy-β-D-gluco-pyranoside 
• 120818-47-5 (4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-p-tolyloxy-tetrahydro-pyran-2-carboxylic acid 

Relevant academic research and scientific papers

Diastereoselective Free-radical Reactions. Part 1. Preparation of 2-Deoxy-β-glycosides by Synthesis and Reductive Decarboxylation of 3-Deoxyulosonic Acid Glycosides

A general procedure for the synthesis of 2-deoxy-β-D-glycosides involving the preparation of 3-deoxyulosonic acid glycosides from glycals and their reductive decarboxylation is described.

Stereoselective Free Radical Reactions in the Preparation of 2-Deoxy-β-D-glucosides

Decarboxylation of the O-methyl, O-p-cresyl and O-3β-cholestanyl glycosides of 3-deoxy-4,5,7-tri-O-benzyl-D-arabino-heptulosonic acid by means of the derived O-acyl thiohydroxamates leads stereoselectively to the corresponding 2-deoxy-β-D-glucosides.