120853-08-9Relevant academic research and scientific papers
Diazo decomposition in the presence of tributyltin hydride. Reduction of α-diazo carbonyl compounds
Tan, Zhongping,Qu, Zhaohui,Chen, Bei,Wang, Jianbo
, p. 7457 - 7461 (2000)
The diazo group of a series of α-diazo carbonyl compounds can be reduced to the corresponding CH2 group by Bu3SnH under Cu(acac)2-catalytic or photochemical conditions. The mechanistic aspects of this reaction were investigated in some detail, and a possible reaction pathway was discussed. (C) 2000 Elsevier Science Ltd.
