120869-79-6

Basic information

• Product Name: Silane, trimethyl[[(1Z)-1-phenyl-1-butenyl]oxy]-
• CAS NO: 120869-79-6
• Molecular Formula: C13H20OSi
• Molecular Weight: 220.387
• Mol File: 120869-79-6.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[[(1Z)-1-phenyl-1-butenyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[[(1Z)-1-phenyl-1-butenyl]oxy]-(120869-79-6)
• EPA Substance Registry System: Silane, trimethyl[[(1Z)-1-phenyl-1-butenyl]oxy]-(120869-79-6)

Safety Data

• Hazardous Substances Data: 120869-79-6(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 56345-77-8 (E)-(1-bromo-1-butenyl)benzene 
• 5796-98-5 bis-trimethylsilanyl peroxide 
• 27617-90-9 Lithiumbutyrophenon 
• 52755-38-1 1-phenyl-2-buten-1-ol 
• 591-51-5 phenyllithium 
• 2648-61-5 2,2-dichloroacetophenone 
• 31151-36-7 ((Z)-2-Chloro-1-phenyl-vinyloxy)-trimethyl-silane 
• 925-90-6 ethylmagnesium bromide 
• 495-40-9 propiophenone 

Downstream Products

• 495-41-0 1-phenylbut-2-en-1-one 
• 70856-07-4 2-nitro-1-phenylbutan-1-one 
• 35660-91-4 (E)-1-phenyl-2-buten-1-one 
• 146790-89-8 Phenyl 1-(4-methylphenyl)propyl ketone 
• 57205-13-7 α-(phenylthio)butyrophenone 
• 1404225-04-2 methyl (R)-3-ethyl-5-oxo-2-phenylcyclopent-1-enecarboxylate 
• 1404224-99-2 methyl (R)-5-((R)-2,2,6,6,7,7-hexamethyl-4-phenyl-3,5-dioxa-2,6-disilaoctan-4-yl)hept-2-ynoate 
• 1404225-00-8 C₂₄H₄₀O₄Si₂ 
• 1151770-34-1 (2R,3S,Z)-methyl 2-(4-bromophenyl)-3-methyl-5-phenyl-5-(trimethylsilyloxy)pent-4-enoate 
• 1151770-35-2 (1S,2S,3R)-methyl 1-(4-bromophenyl)-3-ethyl-2-phenyl-2-(trimethylsilyloxy)cyclopropanecarboxylate 

Relevant articles and documents

Highly regio and stereoselective preparation of Z silyl enol ethers and Z enol esters from ketones via manganese enolates

Mn-enolates are easily and quantitatively obtained under mild conditions (THF, -10°C to rt, 1 h) by treatment of ketones with aromatic Mn-amides such as Ph(Me)NMnZ. They allow to prepare Z silyl enol ethers and Z enol esters in high yields and with an exc

Organosilicon Reducing Reagents for Stereoselective Formations of Silyl Enol Ethers from α-Halo Carbonyl Compounds

Salt-free stereoselective synthesis of silyl enol ethers was achieved by treating α-halo carbonyl compounds with 2,3,5,6-tetramethyl-1,4-bis(trimethylsilyl)-1,4-dihydropyrazine. In this reaction, easily removable trimethylsilyl halides and 2,3,5,6-tetramethylpyrazine were generated as the reaction byproducts. Due to the inertness of the reaction byproducts, we found a one-pot transformation of the in situ generated silyl enol ethers into various α-functionalized carbonyls by reaction with Togni-II reagent or aldehydes.

Intermolecular C-H functionalization versus cyclopropanation of electron rich 1,1-disubstituted and trisubstituted alkenes

Rhodium(II)-catalyzed reactions of aryldiazoacetates with electron rich 1,1-disubstituted and trisubstituted alkenes were systematically studied. The regio-, diastereo- and enantioselectivity of the chemistry was profoundly influenced by the nature of the