120883-44-5Relevant academic research and scientific papers
New Organophosphorus Ligands: Cyclopropanation and Other Reactions of Cumulenes Bearing Diphenylphosphanyl Substituents
Manhart, Stefan,Schier, Annette,Paul, Martin,Riede, Juergen,Schmidbaur, Hubert
, p. 365 - 372 (2007/10/02)
Hydrophosphorylation of 1,4-bis(diphenylphosphanyl)butadiyne with diphenylphosphane leads to the butadiene (Ph2P)2C=CH-CH=C(PPh2)2 (1).Treatment of 1 with dimethylsulfonium methylide gives the vinylcyclopropane (Ph2P)2C=CH-CH(CH2)C(PPh2)2 (2).Compound 2 r
Contributions to the Chemistry and Structures of Tris(diphenylphosphino)ethene and 1,1,4,4-Tetrakis(diphenylphosphino)-1,3-butadiene
Schmidbaur, Hubert,Paschalidis, Christos,Steigelmann, Oliver,Wilkinson, Dallas L.,Mueller, Gerhard
, p. 1857 - 1862 (2007/10/02)
Reaction of tris(diphenylphosphino)ethene (1), obtained by base-catalyzed hydrophosphorylation of Ph2PCCPPh2 with Ph2PH, with 2 equivalents of H3B*OC4H8 affords 1,1-bis(boranatodiphenylphoshonio)-2-(diphenylphosphino)ethene (2).Methylation of 1 with MeI gives the monoquaternary salt 3, the molecular structure of which was determined by X-ray crystallography.A trisulfide 4 is available by treatment of 1 with elemental sulfur. - 1,1,4,4-Tetrakis(diphenylphosphino)-1,3-butadiene (5) was isolated as a byproduct in the synthesis of 1. 1,1,4,4-substitution was established by X-ray analysis of the tetrasulfide 6, obtained by treatment of 5 with elememtal sulfur.Reaction of 5 with 2 equivalents of Mo(CO)6 yields the symmetrical, dinuclear complex 7. - Key Words: Tris(diphenylphosphino)ethene derivatives / 1,1,4,4-Tetrakis(diphenylphosphino)-1,3-butadiene derivatives / Molybdenum complex
