1208989-34-7

Basic information

• Product Name: 2-methylpropane-2-sulfinic acid [1-(2-methyl-1-ylphenyl)ethylidene]amide
• Synonyms: 2-methylpropane-2-sulfinic acid [1-(2-methyl-1-ylphenyl)ethylidene]amide
• CAS NO: 1208989-34-7
• Molecular Weight: 223.339
• Mol File: 1208989-34-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-methylpropane-2-sulfinic acid [1-(2-methyl-1-ylphenyl)ethylidene]amide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methylpropane-2-sulfinic acid [1-(2-methyl-1-ylphenyl)ethylidene]amide(1208989-34-7)
• EPA Substance Registry System: 2-methylpropane-2-sulfinic acid [1-(2-methyl-1-ylphenyl)ethylidene]amide(1208989-34-7)

Safety Data

• Hazardous Substances Data: 1208989-34-7(Hazardous Substances Data)

Upstream product

• 529-20-4 2-methylphenyl aldehyde 
• 196929-78-9 (R)-2-methylpropane-2-sulfinamide 

Downstream Products

• 1133831-71-6 (R(S))-N-((R,E)-1-(2-methylphenyl)hex-2-enyl)-2-methylpropane-2-sulfinamide 
• 1198053-79-0 (1S,2R)-1-((R)-1,1-dimethylethylsulfinamido)-1-o-tolylbut-3-en-2-yl benzoate 
• 1208989-35-8 C₁₃H₁₈F₃NOS 
• 1256350-29-4 C₁₃H₁₅NO 
• 1272676-10-4 C₁₈H₂₉NO₃S 
• 1415337-94-8 C₁₉H₂₂N₂OS₂ 

Relevant articles and documents

Development and Scope of the Arene-Fused Domino Michael/Mannich Reaction: Application to the Total Syntheses of Aspidosperma Alkaloids (-)-Aspidospermidine, (-)-Tabersonine, and (-)-Vincadifformine

The development and application of the arene-fused domino Michael/Mannich route to the tetrahydrocarbazole (ABE) core of Aspidosperma alkaloids is described. The scope of this novel transformation was studied in terms of the nucleophilic component (i.e., N-sulfinyl metallodienamine) and the electrophilic component (i.e., Michael acceptor). The successful application of this methodology toward the concise total syntheses of classical indole alkaloids (-)-aspidospermidine, (-)-tabersonine, and (-)-vincadifformine in 10-11 steps, respectively, is also discussed.

Unprecedented copper(I) bifluoride complexes: Synthesis, characterization and reactivity

To be or not to bifluoride: Two synthetic pathways to unprecedented N-heterocyclic carbene copper(I) bifluoride complexes have been developed (see scheme). Catalytic tests demonstrated that copper(I) bifluorides are very efficient catalysts, which do not