1209-68-3

Usage

InChI:InChI=1/C15H22O/c1-12(9-11-16)7-8-14-13(2)6-5-10-15(14,3)4/h7-9,11H,5-6,10H2,1-4H3/b8-7+,12-9+

Upstream product

• 432-25-7 2,6,6-trimethylcyclohex-1-enecarbaldehyde 
• 162889-29-4 C₉H₁₇LiO₂ 
• 211235-94-8 (E)-5,5-diethoxy-3-methyl-1-(2,6,6-trimethylcyclohex-1-enyl)pent-2-en-1-ol 
• 157886-41-4 (E)-4-iodo-3-methyl-3-buten-1-al, diethylacetal 
• 17075-53-5 3-methyl-1-(2,6,6-trimethylcyclohex-1-ene-yl)pent-1-ene-4-yn-3-ol 
• 79-77-6 4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one 
• 19834-52-7 3-Methyl-1-(2,6,6-trimethyl-cyclohexen-⁽¹⁾-yl)-pentadien-(1,3)-saeure-⁽⁵⁾-nitril 
• 151018-50-7 1-bromo-4-ethoxy-2-methylbuta-1,3-diene 
• 145572-39-0 1-bromo-4,4-diethoxy-2-methylbut-1-ene 
• 145572-38-9 1,2-dibromo-4,4-diethoxy-2-methylbutane 
• 54340-95-3 1,1-diethoxy-3-methyl-3-butene 

Downstream Products

• 1436-55-1 3,7-dimethyl-9-(2,6,6-trimethylcyclohexen-1-yl)nona-2,4,6,8-tetraenal 
• 116-31-4 vitamin A aldehyde 
• 58526-71-9 3-Methyl-1-(2,6,6-trimethyl-cyclohexen-1-yl)-heptatrien-1,3,5-saeure-7-nitril 
• 514-85-2 9-cis vitamin A aldehyde 
• 472-86-6 13-cis-vitamin A aldehyde 
• 116-31-4 all-trans-Retinal 
• 1856-64-0 C₂₁H₂₇NO₂ 
• 4808-01-9 3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propen-1-ol 
• 4951-39-7 3-(2,6,6-timethylcyclohex-1-enyl)propenoic acid 
• 18344-42-8 4-Hydroxyretinal 

Relevant academic research and scientific papers

COMPOUNDS AND METHODS OF TREATING OCULAR DISORDERS

A method of treating an ocular disorder in a subject associated with increased all-trans-retinal in an ocular tissue includes administering to the subject a therapeutically effective amount of a primary amine compound of formula (I); and pharmaceutically acceptable salts thereof.

METHOD FOR PRODUCING SPECIFIC ALPHA,BETA-UNSATURATED ALDEHYDES BY REARRANGEMENT PROCESS

The present invention relates to an improved method for producing specific α,β-unsaturated aldehydes.

METHOD FOR PRODUCING SPECIFIC ALPHA, BETA-UNSATURATED ALDEHYDES

The present invention relates to an improved method for producing specific α, β- unsaturated aldehydes.

Vinyltin acetals in terpenic and nor-terpenic synthesis

Vinyltin acetals obtained by stannylmetallation of homopropargyl acetals with Bu3SnMgMe/CuCN (E configuration) or by titanation of the corresponding alkyltin acetals (Z configuration) have been proved to be efficient storable precursors for the stereoselective synthesis of terpenoids, under mild experimental conditions.Due to the presence of a nucleophilic centre (Csp2-Sn bond) and of a protected electrophilic centre, they are also useful intermediates for an iterative synthesis of retinal and nor-retinoids. - Keywords: vinyltin; acetal; vinyllithium; monoterpenoid; retinal; nor-retinoid

C5-Branched Vinyltin Acetals as Versatile Tools for Terpenic Synthesis

C5-branched vinyltin acetals 1 and 2 obtained by stannylmetallation of homopropargyl acetals with Bu3SnMgMe in the presence of cuprous cyanide have been proved to be efficient storable precursors for the synthesis of terpenoids.

Polyvinylogation Reagents: 1-Lithio-4-trimethylsiloxy-penta-1,3-diene and 1-Lithio-4-ethoxy-2-methyl-buta-1,3-diene

Title products, lithiodienol ethers 6a and 7a, synthetic equivalents of 4-lithio pent-3-ene-2-one and 4-lithio-senecialdehyde were obtained by bromine-lithium exchange.They are choice reagents for the transformations 1 -> 2 and 1 -> 3, respectively.