1209027-05-3Relevant academic research and scientific papers
Halogenated catechols from cycloaddition reactions of η4-(2-ethoxyvinylketene)iron(0) complexes with 1-haloalkynes
Truong, Jimmy,Caze, Vioela,Akhani, Ravish K.,Joshi, Gayatribahen K.,Kakalis, Lazaros,Matsunaga, Nikita,Schnatter, Wayne F.K.
, p. 921 - 923 (2010)
1-Chloroalkynes and 1-bromohexyne undergo cycloaddition reactions with ethoxyvinylketeneiron(0) complexes to form chloro and bromocatechols. With most substituents, the halogen is incorporated ortho to the phenolic hydroxyl group regioselectively. With ch
