120943-79-5

Basic information

• Product Name: (2E)-1-(tert-butyldimethylsilyl)-3-phenylprop-2-en-1-one
• Synonyms: (2E)-1-(tert-butyldimethylsilyl)-3-phenylprop-2-en-1-one
• CAS NO: 120943-79-5
• Molecular Weight: 246.425
• Mol File: 120943-79-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (2E)-1-(tert-butyldimethylsilyl)-3-phenylprop-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (2E)-1-(tert-butyldimethylsilyl)-3-phenylprop-2-en-1-one(120943-79-5)
• EPA Substance Registry System: (2E)-1-(tert-butyldimethylsilyl)-3-phenylprop-2-en-1-one(120943-79-5)

Safety Data

• Hazardous Substances Data: 120943-79-5(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 887588-95-6 3-(tert-butyldimethylsilanyl)-1-phenylprop-2-yn-1-ol 
• 86318-61-8 (tert-butyldimethylsilyl)acetylene 
• 120943-70-6 dimethyl <2-(tert-butyldimethylsilyl)-2-oxoethyl>-phosphonate 
• 120943-69-3 1-(tert-butyldimethylsilyl)-2-iodo-1-ethanone 
• 120820-58-8 2-bromo-1-tert-butyldimethylsilyl-1-ethanone 

Downstream Products

• 144914-79-4 1-(tert-butyldimethylsilyl)-3-phenylpentan-1,4-dione 
• 1266552-00-4 (S,E)-1-(tert-butyldimethylsilyl)-3-phenylprop-2-en-1-ol 
• 1266551-34-1 (R,E)-1-(tert-butyldimethylsilyl)-3-phenylprop-2-en-1-ol 
• 1586870-15-6 N-(1-(tert-butyldimethylsilyl)-3-phenylprop-1-en-1-yl)-p-toluenesulfonamide 
• 1586869-99-9 N-((E)-1-(tert-butyldimethylsilyl)-3-phenylallylidene)-p-toluenesulfonamide 
• 1266551-56-7 (S,E)-3-(tert-butyldimethylsilyl)-1-phenylallyl 4-nitrobenzoate 
• 1266551-53-4 (S,E)-1-(tert-butyldimethylsilyl)-3-phenylallyl 4-nitrobenzoate 

Relevant articles and documents

Lewis Acid-Assisted Photoinduced Intermolecular Coupling between Acylsilanes and Aldehydes: A Formal Cross Benzoin-Type Condensation

Intermolecular carbon–carbon bond-forming reaction between readily available acylsilanes and aldehydes was achieved under photoirradiation conditions with assistance of a catalytic amount of Lewis acid. Nucleophilic addition of photochemically generated s

Stereoselective anti-SN2′ Mitsunobu reaction of α-hydroxy-α-alkenylsilanes

A novel silyl group-directed anti-SN2′ reaction of allylic alcohols under Mitsunobu reaction conditions is described. The Mitsunobu reaction of α-hydroxy-α-alkenylsilanes with a TBS or TIPS group gave the anti-SN2′ product, in which regio- and stereochemical outcomes of the reaction depended on the steric bulkiness of the silyl group.