1209497-03-9

Upstream product

• 1209497-00-6 (1R,4'S,5'S)-1-(5'-tert-butyldiphenylsiloxymethyl)-(2',2'-dimethyl-5'-vinyl[1',3']dioxol-4'-yl)prop-2-en-1-ol 
• 1209497-01-7 (3aR,6aS)-6a-(tert-butyldiphenylsiloxymethyl)-2,2-dimethyl-3a,6a-dihydrocyclopenta[1,3]dioxol-4-one 
• 917-54-4 methyllithium 
• 501-53-1 benzyl chloroformate 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 1309448-36-9 C₃₃H₃₈O₆SeSi 
• 1040918-08-8 (3aR,6aR)-6-(tert-butyldiphenylsiloxymethyl)-2,2,3a-trimethyl-3a,6a-dihydrocyclopenta[1,3]dioxol-4-one 
• 1209497-05-1 (3aS,4S,5R,6S,6aS)-6a-(tert-butyldiphenylsiloxymethyl)-6-phenylseleno-5,6,3a,6a-tetrahydro-2,2,4-trimethylcyclopenta[1,3]dioxole-4,5-diol 
• 1209497-06-2 C₂₆H₃₄O₄Si 
• 1209497-07-3 (3aR,6aR)-6-(tert-butyldiphenylsiloxymethyl)-5-fluoro-2,2,3a-trimethyl-3a,6a-dihydrocyclopenta[1,3]dioxol-4-one 
• 1209497-08-4 C₂₆H₃₃FO₄Si 
• 1309448-38-1 C₂₈H₃₅FO₅Si 
• 1309448-39-2 1-{(3aS,4S,6aR)-6-(tert-butyldiphenylsiloxymethyl)-5-fluoro-2,2,3a-trimethyl-3a,6a-dihydrocyclopenta[1,3]dioxol-4-yl}uracil 
• 1309448-40-5 1-{(3aS,4S,6aR)-6-(tert-butyldiphenylsiloxymethyl)-5-fluoro-2,2,3a-trimethyl-3a,6a-dihydrocyclopenta[1,3]dioxol-4-yl}cytosine 

Relevant academic research and scientific papers

Synthesis of the 5′-Fluoro-2′β-methyl analogues of neplanocin

Synthesis of the 5′-fluoro-2′-β-methyl analogues of neplanocin was carried out. Key intermediate cyclopentenone 19 was prepared from methyl α-D-mannopyranoside by a new approach consisting of ring-closing metathesis, stereoselective introduction of the 2′