120964-38-7

Upstream product

• 120927-57-3 Benzoic acid (3R,4S,5S,6S)-3-benzyloxy-2-((E)-2-ethoxycarbonyl-vinyl)-5-iodo-6-methoxy-tetrahydro-pyran-4-yl ester 
• 120927-57-3 Ethyl (Methyl 3-O-benzoyl-4-O-benzyl-2,6,7-trideoxy-2-iodo-α-D-manno-oct-6(E)-eno-1,5-pyranosid)uronate 
• 120927-56-2 Benzoic acid (2R,3S,4R)-3-benzyloxy-2-hydroxymethyl-3,4-dihydro-2H-pyran-4-yl ester 

Downstream Products

• 120927-66-4 Benzoic acid (1R,2R,3R,4S,5S)-2-benzyloxy-5-dimethoxymethyl-4-ethoxycarbonylmethyl-3-hydroxy-cyclopentyl ester 

Relevant academic research and scientific papers

Radical Cyclization Routes to Bridged Pyranosides as Precursors of Densely Functionalized Cycloalkanes

Glycals derived from hexapyranoses permit the incorporation of iodine at C-2 as well as elaboration of an olefinic residue via the C-5-hydroxymethyl group.Radical cyclization of these functionalities leads to bicyclic systems whose bridge sizes depend on

Intramolecular Radical Cyclizations of 2-Deoxy-2-iodohexopyranoside Derivatives: Routes to Densely Functionalized Carbocycles.

2-Deoxy-2-iodohexopyranosides containing appropriate traps at C6 or C7 undergo radical cyclization to give oxabicyclo or systems whose glicosidic bonds are readily cleaved to afford densely functionalized cyclopentanes or cyclohexanes.