120927-57-3

Upstream product

• 67-56-1 methanol 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 120927-56-2 Benzoic acid (2R,3S,4R)-3-benzyloxy-2-hydroxymethyl-3,4-dihydro-2H-pyran-4-yl ester 
• 137792-77-9 Ethyl 3-O-Benzoyl-4-O-benzyl-1,3,6,7-tetradeoxy-D-arabino-octa-1,6(E)-dieno-1,5-pyranose Uronate 

Downstream Products

• 120964-38-7 (1R,3S,4S,5R,6R,7S)-5-(Benzoyloxy)-6-(benzyloxy)-3-methoxy-2-oxabicyclo<2.2.1>heptane-7-acetic Acid Ethyl Ester 
• 120927-61-9 (1R,3S,4S,5R,6R,7R)-5-(Benzoyloxy)-6-(benzyloxy)-3-methoxy-2-oxabicyclo<2.2.1>heptane-7-acetic Acid Ethyl Ester 
• 120927-66-4 Benzoic acid (1R,2R,3R,4S,5S)-2-benzyloxy-5-dimethoxymethyl-4-ethoxycarbonylmethyl-3-hydroxy-cyclopentyl ester 
• 120927-64-2 Benzoic acid (3aR,4S,5R,6R,6aR)-6-benzyloxy-4-dimethoxymethyl-2-oxo-hexahydro-cyclopenta[b]furan-5-yl ester 
• 120927-61-9 Benzoic acid (1S,3S,4R,5R,6R,7S)-6-benzyloxy-7-ethoxycarbonylmethyl-3-methoxy-2-oxa-bicyclo[2.2.1]hept-5-yl ester 
• 120927-61-9 Benzoic acid (1S,3S,4R,5R,6R,7R)-6-benzyloxy-7-ethoxycarbonylmethyl-3-methoxy-2-oxa-bicyclo[2.2.1]hept-5-yl ester 

Relevant academic research and scientific papers

Radical Cyclization Routes to Bridged Pyranosides as Precursors of Densely Functionalized Cycloalkanes

Glycals derived from hexapyranoses permit the incorporation of iodine at C-2 as well as elaboration of an olefinic residue via the C-5-hydroxymethyl group.Radical cyclization of these functionalities leads to bicyclic systems whose bridge sizes depend on

Intramolecular Radical Cyclizations of 2-Deoxy-2-iodohexopyranoside Derivatives: Routes to Densely Functionalized Carbocycles.

2-Deoxy-2-iodohexopyranosides containing appropriate traps at C6 or C7 undergo radical cyclization to give oxabicyclo or systems whose glicosidic bonds are readily cleaved to afford densely functionalized cyclopentanes or cyclohexanes.