12098-22-5Relevant academic research and scientific papers
Amination of ?-Allylpalladium Chloride Complexes. A Mechanistic Study
Akermark, Bjorn,Akermark, Gunilla,Hegedus, Louis S.,Zetterberg, Krister
, p. 3037 - 3040 (1981)
Conductivity measurements indicate that the reaction of ?-allylpalladium chloride complexes with excess phosphine in THF does not generate cationic ?-allylpalladium complexes.Rather, dynamic ?-allylpalladium complexes are formed.The reaction of neutral ?-allylpalladium chloride complexes with excess phosphine and dimethylamine was compared and contrasted with the same reaction involving preformed cationic ?-allylpalladium complexes, and a change in mechanism was proposed.
