Journal of the American Chemical Society p. 3037 - 3040 (1981)
Update date:2022-08-04
Topics:
Akermark, Bjorn
Akermark, Gunilla
Hegedus, Louis S.
Zetterberg, Krister
Conductivity measurements indicate that the reaction of ?-allylpalladium chloride complexes with excess phosphine in THF does not generate cationic ?-allylpalladium complexes.Rather, dynamic ?-allylpalladium complexes are formed.The reaction of neutral ?-allylpalladium chloride complexes with excess phosphine and dimethylamine was compared and contrasted with the same reaction involving preformed cationic ?-allylpalladium complexes, and a change in mechanism was proposed.
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