Amination of ?-Allylpalladium Chloride Complexes. A Mechanistic Study

DOI: 10.1021/ja00401a021

Source and publish data:

Journal of the American Chemical Society p. 3037 - 3040 (1981)

Update date:2022-08-04

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Authors:

Akermark, Bjorn

Akermark, Gunilla

Hegedus, Louis S.

Zetterberg, Krister

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Article abstract of DOI:10.1021/ja00401a021

Conductivity measurements indicate that the reaction of ?-allylpalladium chloride complexes with excess phosphine in THF does not generate cationic ?-allylpalladium complexes.Rather, dynamic ?-allylpalladium complexes are formed.The reaction of neutral ?-allylpalladium chloride complexes with excess phosphine and dimethylamine was compared and contrasted with the same reaction involving preformed cationic ?-allylpalladium complexes, and a change in mechanism was proposed.

Full text of DOI:10.1021/ja00401a021

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Product name:CH₃CHCHCH₂Pd(P(C₆H₅)3)⁽¹⁺⁾*Cl^(1-)=CH₃CHCHCH₂Pd(P(C₆H₅)3)Cl

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