12101-19-8Relevant academic research and scientific papers
Rhenium polyhydrides stabilized by arsine ligands
Costello, Michael T.,Harris, Terri A.,Walton, Richard A.
, p. 101 - 103 (1996)
The mixed phosphine-arsine ligand Ph2PCH2CH2AsPh2 (arphos) has been used to stabilize the rhenium polyhydrides Re2H8(arphos)2 and ReH7 (arphos). The heptahydride is the first example of a compound of the type ReH7L2 which contains a mixed phosphine-arsine donor set. The spectroscopic and electrochemical properties and stabilities of these complexes are described and compared with data for other complexes of the types Re2H8L4 and ReH7L2.
